Radical Polymerization
(b) Branched polyethylene can be produced via free radical polymerization, primarily due to chain transfer between growing PE chains and monomers. What would be the number-average molecular weight of a branched PE sample if the chain transfer agent is the monomer, the chain transfer coefficient (ktr/kp) is 10-3, and the number-average degree of polymerization is 100 when combination and disproportionation are the only routes of termination? (5 pts)
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